Research News is a digest of science and
technology news items arising
from research and development magazines, newspapers, trade magazines,
newsletters, and other news sources that Valley Research processes
daily for the benefit of its customers everywhere. It is provided
freely to our customers who are free in turn to post or transmit it
to other interested researchers provided only that credit to Valley
Research is given. Research News is updated approximately once a
week.
Rodolfo Carrera, Editor
WEEK OF JANUARY 5, 2009 [No. 774]
Low cost marker diagnosis with new microfluidic glass and plastic protein chip:
researchers at Caltech in Pasadena have made microfluidic chips that can detect
and quantify levels of a dozen different proteins in blood plasma
simultaneously. The test needs only a single drop of blood and takes less than
10 minutes. The group used advanced microfluidic biochip and DNA
microarray-patterning techniques to carve a series of large and small channels
in a thin polymer film. Then, they bonded the film to a glass slide microarrayed
with 12 strips of antibodies to specific indicator-of-disease proteins. The
device separates blood plasma from whole blood cells, then steers the plasma and
the proteins it contains over the antibody arrays for analysis. Fluorescence
analysis then reveals any proteins bound to the microarrays, creating a bar-code
readout of which proteins are present from each blood sample. When different
concentrations of the same antibodies are placed on different microarray strips,
the chips can also determine the abundance of target proteins as well. This
technique should help develop low cost commercial and simple devices for finding
disease protein markers in plasma, decreasing present clinical lab diagnosis
cost by three orders of magnitude to just pennies per test.
For more information:
Materials Research Society Fall Meeting, December (2008); Science December 19
(2008) page 1784.
WEEK OF DECEMBER 29, 2008 [No. 773]
Nanolaser using a current-driven nanotube made:
researchers at the IBM Watson Research Center (NY) have shown how the
integration of carbon nanotubes with high-confinement photonic structures might
lead to different types of active nanoscale photonic devices such as emitters,
detectors, and modulators. Although emission from direct-bandgap,
semiconducting, current-injected carbon nanotubes is weak, spectrally broad,
diffuse, and no directional in nature, the group has streamlined carbon-nanotube
emission by integrating a carbon-nanotube emitter with a planar microcavity. The
nano-emitter is a back-gated, light-emitting field-effect transistor (FET) based
on a semiconducting single-walled carbon nanotube in a planar lambda/2 optical
microcavity formed by two mirrors. The microcavity is fabricated with three
dielectric layer stacks (250 nm PMMA, 22 nm Al2O3, 250 nm SiO) sandwiched
between a top 20-nm thick Au mirror and a bottom 100-nm thick Ag mirror. A
single nanotube is placed on top of the Al2O3 layer and is oriented parallel to
the top and bottom mirror layers for optimum coupling of the nanotube to the
modes of the microcavity. The Au mirror is partially reflecting to allow for
outcoupling of the cavity mode. The result is a spectral narrowing of the
free-space emission of the nanotube that matches the spectral position, line
shape, and linewidth of the longitudinal mode of the microcavity, regardless of
the nanotube dimensions.
For more information:
Laser Focus World, December (2008) page 21; Nature Nanotechnology, August 24
(2008).
WEEK OF DECEMBER 22, 2008 [No. 772]
Quantum state engineering tooling established:
researchers at the University of Florence have shown that if one photon is
removed from a beam of coherent laser light, the light remains in the same
coherent state. And therefore, they have shown that a coherent state is an
eigentstate of the annihilation operator. It was already known (shown
theoretically in 1963) that the addition and subtraction of single photons from
coherent light does not affect its coherence and that changing the number of
photons only changes the amplitude of the beam. In the experiment, a relatively
intense laser beam is first passed through a highly-reflective beam splitter,
which deflects most of the light into a coherent reference beam. The rest of the
light travels straight through the beam splitter and emerges as a relatively
weak but still coherent beam. This beam is then sent through a second beam
splitter, which is extremely inefficient and only occasionally diverts a photon
away from the beam and into a very sensitive detector. Then they looked for any
changes in the coherence of the beam by recombining it with the reference beam
in an interferometer. The group has put together "creation and annihilation"
operators that add and remove photons and have established the noncommutivity of
these operators.
For more information:
Physicsworld, December 17 (2008); New Journal of Physics.
WEEK OF DECEMBER 15, 2008 [No. 771]
Prostate stem cells identified:
researchers at Genentech in San Francisco have identified a new marker CD117
that is specific to normal prostate stem cells (PSC) from which cancer stems
cells
might be derived. They looked in a region in the prostate considered to be the
stem cell niche. The CD117 is expected to be a marker in human PSCs as well so
it should help in the identification of human-prostate-cancer stem cells. This
marker completes a set of three other already known cell-surface proteins common
to candidate PSCs that together were not specific enough to isolate only
potential PSCs. Combined, the four markers form a sort of PSC barcode that can
be used to sort out cells from prostate tissue. The identified normal adult stem
cells were proven to give rise to all of the cell types within a prostate in
mice. These individual cells were used to generate prostates. If cancer stem
cells are normal stem cells that have accumulated mutations and are responsible
from growth of tumors, a therapy that specifically targets these subpopulations
of cells would be needed for a more effective cancer treatment. This is required
because, like normal stem cells, these cancer stem cells are long-lived and slow
growing, so they are not killed off by treatments that target rapidly dividing,
non-stem cancer cells.
For more information:
Nature, December 11 (2008) pages 804 and XIII.
WEEK OF DECEMBER 8, 2008 [No. 770]
Artificial control of paralyzed limbs using cortical cells:
researchers at the University of Washington have shown that Macaca nemestrina
monkeys can directly control stimulation of muscles using the activity of
neurons in the motor cortex, thereby restoring goal directed movements to a
transiently paralyzed arm. Neurons could control functional stimulation equally
well regardless of any previous association to movement. This is the first
demonstration that direct external connections between cortical cells and
muscles can compensate for interrupted physiological pathways and restore
volitional control of movement to paralyzed extremities.
For more information:
Nature, December 4 (2008) page 639.
Heat transport within Earth's mantle dominated by radiation:
German scientists have obtained the near-infrared and optical absorption spectra
of silicate perovskite (the main constituent of the lower mantle) to 125
gigapascals (1.25 Matm). The compound remains quite transparent up to the
pressures at the core-mantle boundary. Estimates of radiative thermal
conductivity derived from these spectra approach 10 w/m/K at lowermost mantle
conditions. This implies that heat transport is dominated by radiation. The
increase in radiative conductivity with temperature is less pronounced than
expected from a T3 dependency.
For more information:
Science, December 5 (2008) page 1529.
WEEK OF DECEMBER 1, 2008 [No. 769]
Simple primary electronic-based thermometer standard demonstrated:
researchers at the Helsinki University of Technology and NEC in Japan have
invented a type of electronic thermometer that relates temperature directly to
the Boltzmann constant and that is simpler to manufacture than others previously
proposed. They use the fact that the electrical conductance of an array of
tunnel junctions (tiny bits of insulator sandwiched between two metals) changes
with temperature. Their single-junction thermometry technique provides good
accuracy of measurements at low temperatures (≤ 1 K) by arranging the
tunnel
junctions in a circuit such that the conductance depends on the properties of
just one junction. The tunnel junctions are created by first allowing a very
thin layer of aluminum oxide to grow on the surface of µ-wide aluminum
electrodes. Another electrode is then deposited on the oxide, creating a
metal-insulator-metal junction through which electrons can tunnel. By scanning
an applied voltage and measuring the current through the junction, a dip is
observed (a dramatic drop in conductance occurs at small voltages with minimum
value at 0 volts and rising values around 0 volts for positive and negative
voltages). The dip width is proportional to the Boltzmann constant multiplied by
the temperature.
For more information:
Physicsworld, December 2 (2008); Phys. Rev. Lett., November 14 (2008) page
206801.
WEEK OF NOVEMBER 24, 2008 [No. 768]
Photonic nanomechanical principle shown:
researchers at Yale University have shown a new optical force that can be
detected and exploited to move an entire semiconductor device. When they passed
concentrated light through an embedded nanomechanical waveguide resonator they
induce bending. The optical force causing this displacement can be measured as a
change in the coupling between the resonator and its dielectric substrate. The
force can be as high as 8 pN /µ/mw, enough to move nanoscale machinery on
a chip. This optical force acts perpendicular to the direction of the light
beam, so some electrical-based complex nanocomponents like mirrors would not be
required in all-optical CMOS compatible photonic nanomechanical systems.
For more information:
Nature, November 27 (2008) pages 480 and 458; Physicsworld, November 26 (2008).
Law for iceberg calving discovered:
a group of scientists in Pennsylvania State University and elsewhere in the US,
have come up with a simple law that explains much ice-shelf break-up, an
important ingredient in predicting the future of the Greenland and Antarctic ice
sheets under the global warming process. Ice calving is simply proportional to
the along-flow rate of spreading times the width of the shelf times the
thickness of the shelf. For narrow shelves between two ridges, the sides hold
back the ice, slowing the overall movement and making it harder to break the
ice. Thicker ice shelves tend to spread more quickly. The spreading rate can be
calculated from ice thickness and other variables already solved in
well-established numerical models.
For more information:
Science, November 28 (2008) page 1344; Physicsworld, November 27 (2008).
WEEK OF NOVEMBER 17, 2008 [No. 767]
Molecular evolution tracked during a chemical reaction:
a group lead by Japanese researchers has recorded transient impulsive Raman
spectra during ultrafast photoisomerization of cis-stilbene in solution
(important in the photochemistry of vision). The results demonstrate a gradual
frequency shift of a low-frequency vibration of previously considered excited
but stationary molecular parts. They observe the evolution of a vibrational
motion representing nuclear motions with periods of 160 fs. The technique allows
for tracking of molecular vibrations during reactions and the characterization
of global motions of the entire molecule.
For more information:
Science, November 14 (2008) pages 1073 and 1056.
An excess of galactic cosmic-ray high-energy electrons detected:
an international group of researchers has detected an excess of a factor of
~3 in the flux of cosmic-ray electrons in the 300 - 800 GeV range using the
ATIC calorimeter experiment in a balloon high above the Antarctic. The
discovery comes right after a similar report of an excess of cosmic-ray
positrons. The source of each excess is not known but both indicate either new
astrophysical sources or new physical processes. There is controversial
speculation that both could be signatures of WIMP (weakly interacting massive
particles, a leading candidate for dark matter) annihilation.
For more information:
Physicsworld, November 20 (2008); Nature, November 20 (2008) pages 362 and 329.
WEEK OF NOVEMBER 10, 2008 [No. 766]
Cyclic stretching micro-mechanical AC generator:
a group lead by researchers at the Georgia Institute of Technology have used a
zinc-oxide wire to create an AC current ~8 pA and a voltage of ~50 mV
(~15 times more than with other micro generators). The tiny device
generates electric power as it is stretched and then released. They bonded a
single wire (4µ thick and 200µ long) onto a flexible insulating
polyimide film. The wire is stretched by simply bending the film. The resulting
voltage is caused by the piezoelectric effect. No sliding contacts at the ends
of the wire are involved. To make an AC generator they connected one end of the
wire to a Schottky barrier that allows current flow in only one direction. When
the wire is stretched a voltage builds up across the wire, and then, when the
wire is allowed to relax, a similar but opposite voltage appears across the
wire. An AC voltage of about 50 mV is generated when the wire is stretched by
about 0.1% and then released at a rate of 22 cycles per minute by a
motor-driven mechanical arm. The device converts mechanical energy to electrical
energy with an efficiency ~6.8%. Many wires can be integrated together
to boost both the power and voltage output. Increasing the rate at which a wire
is strained boosts both the output voltage and current.
For more information:
Physicsworld, November 12 (2008); Nature Nanotechnology, November 9 (2008).
WEEK OF NOVEMBER 3, 2008 [No. 765]
Basic circuit models single-cell learning:
scientists at the University of California San Diego have linked a resistor R,
an inductor L, and a capacitor C in series and then placed a memresistor across
the capacitor to make an electronic circuit that is an analogue of how a
single-celled organism learns. The recently realized memresistor has a
resistance that varies according to the charge that has flowed through it and
then, provides the memory needed for learning. When the external voltage is
stable or varying non-periodically, the memresistor exists in a low-resistance
state (which dampens the oscillation in voltage across the memresistor set up by
the LC). However, when the external voltage varies periodically with a frequency
close to the LC resonant frequency, the memresistor switches to a high
resistance state, and the oscillations are much less damped. This
high-resistance state can persist for so long that a single voltage dip input in
the future can also trigger low-damped oscillations. That is, after the circuit
receives a series of dips at its input it then remembers that, given just a
single dip in the future, it should continue to produce a periodic output. Since
periodic signals trigger the memory mechanism, it is expected that the circuit
can be used to recognize particular inputs and then, carry out pattern
recognition.
For more information:
Physicsworld, October 31 (2008).
WEEK OF OCTOBER 27, 2008 [No. 764]
Fast and low cost sequencer proposed:
a scientist at California State University Northridge has proposed a way of
sequencing an entire DNA strand without the need for blasting and supercomputer
processing used in the conventional shotgun method. The technique involves
cutting a very narrow slit (nanogap) in a graphene sheet. A voltage is applied
perpendicular to the graphene's surface, which causes the DNA strand to pass
slowly through the slit one base at a time. A second voltage is applied across
the slit and electrons are able to tunnel across the nanogap via the base that
happens to be passing through the slit. There are four different types of bases
in a DNA molecule and each should support a different tunneling current,
allowing the base type to be identified. While the idea of sequencing DNA by
sending it through a tiny gap is not new, previous schemes had relied on using
separate materials for the membrane and electrodes, and aligning the two
materials has proved difficult. This design gets around this problem by having
the graphene function as both membrane and electrode. If run continuously, this
sequencer could read the whole human genome in 2.5 hrs. The detector could be
made from a graphene sheet sandwiched between glass plates that are held
together by van der Waals forces.
For more information:
Physicsworld, October 28 (2008).
WEEK OF OCTOBER 20, 2008 [No. 763]
A single molecule trapped at room temperature:
scientists at Harvard have used an Anti-Brownian Electrokinetic (ABEL) trap to
pin down one molecule at a time in an aqueous environment at room temperature.
The fluorescently labeled molecule is tracked in an optical microscope and its
random motion slowed by carefully timed surrounding electrode pulses. The
electrodes are at distance that ensures no pollution of the sample environment
by chemical effects. The µw electric kicks are imparted to the molecule
along
micro-channels in an underlying chip.
For more information:
Physics New Update, October 23 (2008).
Prebiotic chemistry even more efficient than thought:
American and Mexican researchers have used liquid chromatography and mass
spectrometry techniques to discover that a particular variation of the
spark-flask apparatus experiments used in the "primordial soup" experiments by
Miller at the University of Chicago in the early 50's, produced a wider variety
of amino acids than initially reported by Miller. The classical experiments
produced an electric discharge into a flask with CH4, NH3, H2, and H2O. The
non-classical apparatus had an additional hot water mist added to the classical
spark flask, simulating a water vapor-rich volcanic eruption.
For more information:
Science, October 17 (2008) page 404; Chem. Eng. News, October 20 (2008) page 12.
WEEK OF OCTOBER 13, 2008 [No. 762]
Spin Seebeck effect observed for the first time:
Japanese scientists have discovered that a current of spin-polarized electrons
can be generated by creating a temperature gradient along a length of a magnetic
metal. The group has reported the observation of the thermal generation of
driving power (or voltage) for electron spin. Using a recently developed
spin-detection technique that involves the spin Hall effect, they have measured
the spin voltage generated from a temperature gradient in a metallic magnet.
This thermally induced spin voltage persists even at distances far from the
sample ends, and spin can be extracted from every position in the magnet simply
by attaching a metal. The team first deposited a 20 nm thick layer of a
permanent magnet alloy (Ni81Fe19) onto a Sa substrate to create a sheet 6 mm long
and 4 mm wide. The sheet was magnetized in the long direction (same direction as
the temperature gradient). That causes an excess of spin-up electrons to build
up at the cold end of the sheet and an excess of spin down electrons at the warm
end. The spin Seebeck effect allows the pass of a pure spin current (a flow of
electron spins without electric currents) over a long distance (mm's). This
discovery is directly applicable in the production of voltage generators for
driving spintronic devices.
For more information:
Nature, October 9 (2008), pages 778 and 741; Physicsworld, October 8 (2008).
WEEK OF OCTOBER 6, 2008 [No. 761]
Eliminating the quantum-mechanical stickiness of MEMS and NEMS:
scientists at the Los Alamos laboratory in New Mexico have proposed a quite
promising way to manipulate the Casimir force to make micromachines and
nanomachines run smoother and with diminished or no friction at all. The idea is
basically to coat the surfaces with magnetic metamaterials engineered to support
eddy currents that compensate for the Casimir attraction. The copensation would
come about because the virtual photons would induce electromagnetic fields in
the surfaces that would push them apart so strongly that they would overwhelm
the pressure of virtual photons squeezing the plates together.
For more information:
For more information: IEEE Spectrum, October (2008), page 18.
Easy scale of vertical solid surfaces with nanoengineered pads:
researchers at the Georgia Institute of Technology have made a structure that
looks at least similar to a gecko lizard foot using chemical vapor deposition of
an ethyne-hydrogen-argon gas over a silicon substrate. By introducing an iron
catalyst on the substrate and controlling the temperature and duration of
deposition, they ended up with an array of vertical nanotubes with curly
entangled tops. The material exhibits an anisotropic adhesive force distribution
of 100 Ncm-2 (an order of magnitude greater
than a gecko foot) due to the shear-induced alignments of nanotube tops. If
stuck to a wall it will resist a strong downwards tug, but if it is pulled
directly away, it will peel off easily.
For more information:
Science, October 10 (2008), page 238; Physicsworld, October 9 (2008).
WEEK OF SEPTEMBER 29, 2008 [No. 760]
Room temperature MRI with single-spin sensitivity and nano resolution:
scientists at both Harvard and Stuttgart Universities have developed a new
approach that exploits a single spin associated with a special flaw in diamond
(nitrogen vacancy impurity center) to detect magnetic fields on the nanoscale.
The single spin can be placed on the tip of a SPM to pick up signals by the spin
of an electron or an atomic nucleus placed nearby. The probe spin can feel the
presence of any magnetic fields created by nearby electrons or nuclei, which
cause a shift in its EPR frequency. Owing to the ultralong relaxation times of
N-vacancy electron spins in diamond, single spin MRI is possible and operates
under ambient conditions.
For more information:
Nature, October 2 (2008), pages 644, 648 and 606; Physicsworld, October 2
(2008).
Protein motion observed in the nanosecond time scale:
an international team of researchers at the ESRF in Grenoble has developed a
synchrotron-based structural analysis technique, TR-WAXS (time-resolved
wide-angle X-ray scattering), to observe the kinetics of protein conformational
changes down to the nanosecond range (the popular existing WAXS has been limited
to millisecond time resolution) under nearly physiological conditions. They
observed conformation changes in hemoglobin caused by photodissociation of CO.
Existing spectroscopic techniques with equivalent or better time resolution help
study protein conformational changes, but they do not provide the detailed
structural data that TR-WAXS does.
For more information:
Chem. Eng. News, September 29 (2008), page 11; Nature Methods, September 21
(2008), page 881.
WEEK OF SEPTEMBER 22, 2008 [No. 759]
Measuring the basic unit of muscle contraction:
scientists at Stanford University in California have created a minimally
invasive microendoscopy system that images basic contractile units of striated
muscle (sarcomers composed of myosin motors and acting filaments) at work. They
adapted a laser-scanning microscope with the objective focusing ultrashort
pulsed laser illumination from a wave-length-tunable Ti:Sa laser onto the face
of a gradient refractive index microendoscope. The excitation and resulting
emission traveled part of the way along the same path, with a dichroic mirror
sending the emission off to a PMT for detection.
For more information:
Biophotonics International, September (2008), page 20.
Geomagnetic field flips due to interaction between two core layers:
researchers at the California Polytechnic University and the University of
Wisconsin-Madison have measured ancient field patterns frozen into volcanic
rocks to discover that there is a non-axial dipole component of Earth's magnetic
field. The axial dipole main component is caused by convective flow deep within
the liquid Fe core and is prevalent on Earth's surface. The weaker newly
identified component comes from the top of the outer core and it seems to be the
cause of the flipping that has occurred at times on Earth's magnetic field.
For more information:
Physicsworld, September 25 (2008); Science, September 26 (2008), pages 1800 and
1756.
WEEK OF SEPTEMBER 15, 2008 [No. 758]
Nanosecond TEM:
scientists at the Lawrence Livermore Lab in California have used a photoemitted
electron pulse (laser pumped electron gun) to probe dynamic events with snapshot
diffraction and imaging at 15-nanosecond resolution inside of a dynamic
transmission electron microscope (TEM). The moving reaction front of reactive
nanolaminates is observed in situ. Time-resolved images and diffraction show a
transient cellular morphology in a dynamically mixing, self-propagating reaction
front, revealing brief phase separation during cooling, and thus provide
insights into the mechanisms driving the self-propagating high-temperature
synthesis.
For more information:
Science, September 12 (2008), pages 1472 and 1413.
Stable quantum gas of polar molecules created:
a group lead by researchers at NIST-Boulder has created the first stable
ultracold (350 nK) dense (1012 cm-3) quantum gas of molecules with large electric
dipole moments. Unlike other quantum gases, the molecules interact with each
other over relatively large distances. The group starts with a very cold gas
that is a mixture of K/Rb atoms confined by a laser beam and within a magnetic
field. A two wavelength NIR laser is used to cause the molecules to give up
their internal energy as photons of red light, which exit the gas without
heating it. This leaves the majority of the molecules in their lowest
vibrational and rotational energy states. The team measured the dipole moment by
applying a small electric field to the gas and determining the resultant shift
in the molecule's energy levels using laser spectroscopy. Qbits made from such
molecules would be robust to interference from outside influences and could be
manipulated by the simple application of an electric field.
For more information:
Science Online and Physicsworld, September 18 (2008).
WEEK OF SPTEMBER 8, 2008 [No. 757]
MicroTesla brain MRI demonstrated:
scientists at the Los Alamos Lab in New Mexico have obtained images of a living
human brain using pre-polarization at 30 mT and image collection at just 46
µT. Using such small fields means that the frequency of the signals
produced by the oscillating nuclear spins are similarly reduced from the usual
RF range to around an audible 2 kHz. The magnetic resonance signals were
detected using superconducting quantum-interference devices (SQUIDs) capable of
detecting both nuclear spins (MRI) and neuronal activity fields for simultaneous
magnetoencephalography (MEG) recording.
For more information:
Journal of Magnetic. Resonance, September (2008), page 115; Nature, September 4
(2008) page 43.
Laser frequency comb used in astronomical spectrum calibration:
a group of German and Australian researchers have demonstrated the use of a
laser frequency comb for wavelength calibration of a telescope. They combine the
fiber optic laser frequency comb (spectrum of a fs mode-locked laser that
delivers pulses at rep rates of ~1 GHz with equally spaced wavelengths)
with a
solar observation to precisely measure and calibrate the wavelengths of the
spectrogram. They obtain absolute calibration with an equivalent Doppler
precision of 9 m/s at ~1.5 µ. This technique promises wavelengths to
be
measured with a stable precision of 0.1 ppb and Doppler accuracies of 1 cm/s per
year as required for real time measurement of the Universe acceleration.
For more information:
Science, September 5 (2008), pages 1335, 1301, and 1268.
WEEK OF SEPTEMBER 1, 2008 [No. 756]
Room temperature catalyst for disposal of inert fluorocarbons:
scientists from the Brandeis University in Boston have used a class of
carborane-supported, highly electrophilic silylium compounds, to show that
silylium-carborane catalysts are long-lived catalysts for hydrofluorination
(conversion of very unreactive C-F bonds to C-H bonds) of trifluoromethyl and
nonafluorobutyl groups by widely accessible silanes under mild conditions. The
reactions are completely selective for aliphatic carbon-fluorine bonds in
preference to aromatic carbon-fluorine bonds.
For more information:
Chem. Eng. News, September 1 (2008), page 13; Science August 29 (2008) pages
1188 and 1168.
Geodynamo simulation gets worse as conditions are made more realistic:
researchers at Yokohama have used the 4,096 processor Earth Simulator
supercomputer to do simulations of the geodynamo with conditions closer to
reality than ever before. They find that both the convection flow and the
magnetic field structures are qualitatively different from those found before.
The convection takes the form of sheet plumes rather than the columnar cell
structures usually found. A laminated flow pattern still acts as an efficient
dynamo but the magnetic field produced is not predominantly dipolar.
For more information:
Nature, August 28 (2008), pages 1106, 1058, and VII.
WEEK OF AUGUST 25, 2008 [No. 755]
Galactic emission filaments supported by magnetic fields:
scientists from Cambridge and elsewhere in UK and the US have used imaging from
the Hubble Space Telescope to resolve long thin strands (thread-like structures)
within the nebulosity of the emission-line filaments in the giant elliptical
galaxy NGC 1275 at the center of the Perseus Constellation galaxy cluster. The
bright filaments of ionized gas are dragged out from the center of the galaxy
(where a black hole emits jets of gases) by radio-emitting bubbles rising
buoyantly in the hot intracluster gas. When the bubbles become buoyant they drag
some of the cooler gas from the center of the galaxy outwards (the observed
filaments are simply this gas being dragged outwards). The filaments look as
static markers of the feedback process by which energy is transferred from the
central massive black hole to the surrounding gas. These filaments remain stable
(they are thought to be at least 100 Myr old) despite the disruptive effects of
extreme pressure by tidal shear forces and extreme heat by very hot (40 MK)
surrounding gases. The team concludes that galactic magnetic fields
(~10-4 Gauss) within the threads maintain the filament's
structure by holding the pressure balance with the surrounding gas. The
stabilization of the filaments allows for the accumulation of a large mass of
cold gas that delays star formation.
For more information:
Nature, August 21 (2008), pages 968, IX and XI.
WEEK OF AUGUST 18, 2008 [No. 754]
Nanopillar magnetic moment flipped in one nanosecond:
scientists from the PTB in Germany have shown that by adequately controlling the
temporal shape and length of a pulse of spin-polarized electrons and by applying
small constant magnetic field, they can reduce the present flipping time of
magnetic nanopillars by an order of magnitude. This could lead to magnetic
access random memories that are as fast and as dense as conventional memory
chips but less energy consuming and persistent after switching off the electric
supply. Commercial GHz MRAMS might be a couple of years away now.
For more information:
Physicsworld, August 21 (2008); Phys. Rev. Lett., to be published.
Solar cells with over 40% efficiency :
researchers at the Department of Energy NREL lab in Colorado, have produced a
record solar-cell efficiency with a thin and light photovoltaic device that
converts to electricity 40.8% of the concentrated sunlight it receives in
tests. The group uses a high-sunlight conversion metamorphic triple-junction
(with mismatched semiconductor lattices) solar cell made from a composite of
GaInP and GaInAs materials, to split the solar spectrum into three equal parts
to be absorbed by each of the cells three junctions.
For more information:
Chem. Eng. News, August 18 (2008), page 26.
WEEK OF AUGUST 11, 2008 [No. 753]
Not instant quantum entanglement:
scientists from the University of Geneva have placed a lower boundary on the
speed of any possible entanglement signal between entangled photons. They
performed a test over more than 24 hrs between two villages separated by 18 km
and approximately east-west oriented, with the source of entangled photons
located precisely in the middle of the optical path. They calculated that if a
privileged reference frame exists (with Earth's speed on it < 0.001 c), the
entanglement signal speed would have to be > 10,000 c.
For more information:
Nature, August 14 (2008), page 861; Physicsworld, August 13 (2008).
Working visual memory capacity explained:
researchers at the University College London have shown that visual memory
capacity is not fixed by the number of objects (currently understood as four),
but rather is a limited resource that is shared out dynamically between all
items in the visual scene. This resource can be shifted flexibly between
objects. The proportion of resources allocated to each item determines the
precision with which it is remembered.
For more information:
Science, August 8 (2008), page 851.
Dark energy identified by direct observation:
scientists from the University of Hawaii have analyzed the glow of the cosmic
microwave background and have focused on a single sample of the biggest
superclusters and supervoids. They have clearly shown how the superclusters are
being stretched apart (rather than stay the same as predicted by general
relativity). This is after a decade of the repulsive dark energy idea, the first
time that its effect is neatly and reliably seen on a direct measurement
(amounting to a millionth of a Kelvin photon energy variation).
For more information:
Physicsworld, August 8 (2008)
WEEK OF AUGUST 4, 2008 [No. 752]
Ballistic molecular junctions fabricated:
an international team lead by researchers from the University of Leiden have
fabricated the first highly conductive molecular junctions by forming a direct
metal-carbon bond between a single organic molecule (benzene) and a metal (Pt)
electrode. They verified that electrons are conducted easily between the two and
measured the conductance of these devices to be the maximum value possible for a
single electron channel.
For more information:
Physicsworld, August 2 (2008); Phys. Rev. Lett., to be published.
Electrolysis simplified:
scientists at MIT have devised a novel cobalt phosphate catalyst for water
splitting that forms in situ on the surface of an indium tin oxide electrode.
This is a vast departure from expensive pt-based systems that require strongly
basic or acidic conditions, operate at high temperature, and may never be
economically viable on an industrial scale. The catalyst is made from
inexpensive Co salts and K3PO4 buffer at neutral pH.
For more information:
Chem. Eng. News, August 4 (2008), page 7; Science, August 1 (2008), page 620.
Abrupt climate change in a year:
an international team lead by researchers from the University of Copenhagen have
measured multiple climate proxies (like 18O for
local temperature, D for ocean surface temperature, dust for Asian desert
status, and Na for marine sea salt) in a single ice core from Greenland.
Measuring several parameters in the same ice eliminates problems in trying to
intercalibrate data from different sites. High-resolution measurements show
yearly climate changes during two abrupt warmings within the last deglaciation.
For more information:
Science, August 1 (2008), pages 680, 650 and 608.
WEEK OF JULY 28, 2008 [No. 751]
Plasma collimator for diode lasers:
researchers at Harvard University and Hamada's Photonics have used a patterned
metallic film on the output facet of a semiconductor laser to absorb divergent
light and reemit it in one direction. The film has a slit 2µ wide;
adjacent
to a series of parallel grooves 0.8µ wide, 1.5µ deep and separated
by
8.9µ. The laser emits at 9.9µ. Some laser light is absorbed creating
surface plasmons (collective electron excitations) on the surface of the film.
The plasmons propagate across the film and are scattered by the grooves, which
results in their conversion back into light with the same wavelength as the
laser. The divergence of the plasmon-collimated laser was about 2.4 deg (vs. 63
deg for the bare laser).
For more information:
Physicsworld, July 31 (2008); Nature Photonics, to be published.
Triggering of Earth's aurora sub-storms understood:
researchers working on NASA's Themis mission have uncovered a mechanism that
drives the Northern and Southern Lights. Auroras form by the collisions of
electrons and other charged particles in the magnetosphere. Occasional substorms
create increases in size, brightness and coloring. Themis has spotted an
isolated substorm shortly before a network of ground-based observatories
detected an auroral brightening over the northern US. The data collected
indicates that the solar wind induces magnetic field reconnection releasing
magnetic energy and creating a substorm.
For more information:
Physicsworld, July 25 (2008); Science, to be published.
WEEK OF JULY 21, 2008 [No. 750]
Liquid-based deformable mirror demonstrated:
researchers at Laval University in Quebec have built the first deformable liquid
mirror from a magnetic liquid. They made their mirror from a ferrofluid
containing tiny particles of magnetite (Fe3O4) each about 10
nm in diameter. When ferrofluids are exposed to a magnetic field, the bulk of
the liquid becomes magnetized and its surface acquires a shape to minimize the
energy of the system (this involves gravitational and magnetic forces as well as
the surface tension of the liquid). The ferrofluid is contained in a dish that
sits above a triangular array of 37 magnetic coils, each 5 mm in diameter. By
controlling the current of each coil, the surface profile of the mirror can be
manipulated at near MHz frequency.
For more information:
Physicsworld, July 24 (2008).
Trick to increased catalytic efficiency identified:
scientists at the Dalian Institute of Chemical Physics have shown that confining
metallic nanoparticles inside carbon nanotubes (CNT) alters the redox properties
of the particles and can enhance their effectiveness as catalysts. They used a
solution-phase method aided by ultrasonication to selectively deposit iron oxide
nanoparticles inside CNTs. These particles are precursors for the catalyst used
in FT synthesis, a C-coupling method for making synthetic fuels from mixtures of
CO and H. They find that confined particles are more prone to chemical reduction
than particles attached to the exterior of the nanotubes.
For more information:
Chem. Eng. News, July 14 (2008) page 9; J. Am. Chem. Soc., to be published.
WEEK OF JULY 14, 2008 [No. 749]
Pumped atom laser demonstrated:
researchers at Australian National University have situated a lasing
Bose-Einstein Condensate (BEC) some 8 µ beneath a second BEC, so that it
can
be drip fed with atoms from above. As the atoms from the upper BEC are falling
they are slowed by an optical laser pointed upwards, which forces each atom to
absorb a photon. Shortly after, the atoms emit their own photon downwards,
thereby slowing their descent further. Then the atoms from the upper BEC join
the lasing BEC without disturbing it, and without creating any noise.
For more information:
Nature Physics, July 11 (2008); Physicsworld, July 17 (2008).
Graphene the strongest material ever:
researchers at Columbia University have shown grapheme to be the strongest
material in the world due to the robustness of it covalent C-C bond. They
indented graphene films, placed over holes on a Si wafer, using an AFM with a
diamond tip with a radius of 20 nm (conventional Si tips would break before the
grapheme breaks). If a sheet of cling film (with a typical thickness of 100
µ) were to have the same strength as pristine graphene, it would require a
force of over 2 tons to puncture it with a pencil. The measured strength is >
200 times that of structural steel and > 20 times that of advanced C fibers.
For more information:
Science, July 18 (2008) page 385; Physicsworld, July 17 (2008); Chem. Eng. News,
July 21 (2008) page 46.
Single hydrogen atom seen:
scientists at the University of California, Berkeley have used a transmission
electron microscope (TEM) to see a single H atom, the first time that a TEM has
been used to image such a light atom. A graphene sheet was used as substrate
because of its strength while being just an atom thick. Graphene has minimal
influence when imaging the overlying material of interest (the carbon atoms
within the graphene are invisible to the TEM).
For more information:
Nature, July 17 (2008) page 319 and 283; Physicsworld, July 16 (2008); Chem.
Eng. News, July 21 (2008) page 9.
WEEK OF JULY 7, 2008 [No. 748]
Directed assembly of carbon nanotubes for network thin-film transistors:
esearchers at Stanford University and Samsung have devised a way to sort
single-walled carbon nanotubes (SWNTs) according to their chirality by simply
functionalizing the surface of Si. SWNTs are produced as a mix of both
semiconducting and metallic nanotubes depending on their chirality. The group
found that semiconducting nanotubes preferentially cling to substrates with a
coating of primary amines, while metallic tubes hold fast to substrates
functionalized with phenyl groups. So they added functional group coatings to
the surface of Si substrates and then applied SWNTs via spin coating. From a
typical SWNT blend, the team was able to make transistors enriched with
90-95% of the nanotubes of desired chirality. The technique allows for both
efficiently separating the two types of nanotubes and to pattern them onto a
substrate as thin films. In just one step they formed the heart of a transistor
(i.e., the critical channel between electrodes made of aligned, densely packed
semiconducting nanotubes) that turned off and on much more efficiently than
previous transistors made with bunches of nanotubes (on / off ratio as high as
900,000) and comparably to Si. The new technique is amenable to large-scale
fabrication.
For more information:
Science, July 4 (2008) pages 101 and 12; Chem. Eng. News, July 7 (2008) page 8;
Physicsworld, July 4 (2008).
WEEK OF JUNE 30, 2008 [No. 747]
Ordered mesoporous metals prepared:
researchers at Cornell University have developed a synthesis for ordered
metallic materials that feature pores in the previous unattainable 10 nm size
range. It has been difficult to achieve because metals have high surface
energies that favor low surface areas that cause particles to cluster. The group
used ionic-liquid ligands to render the 1.8 nm Pt particles soluble preventing
their agglomeration. When combined with block copolymers, the metal particles
self-assemble to form ordered metal-organic hybrid structures. Then they use
various heat treatments and etching procedures to remove the organic components.
For more information:
Chem. Eng. News, June 30 (2008) page 10; Science, June 27 (2008) page 1748.
Desalinization through nanomembranes shown:
scientists at the Lawrence Livermore Lab have created filtration membranes by
embedding nanotubes in a SiN matrix and then uncapping the ends of the tubes by
an etching process that also introduced carboxylate groups around tube
entrances. The carboxylate groups form a ring of negative charges through which
ions must pass to enter the tubes. In this way, the group has demonstrated that
arrays of densely packed, vertically aligned carbon nanotubes can serve as
membranes to filter ions out of water while allowing the water to flow
significantly faster than through conventional filters. In these nanomembranes,
ion exclusion stems primarily from electrostatic rather than spatial effects.
For more information:
Chem. Eng. News, June 23 (2008) page 29; Proc. Natl. Acad. Sci. USA to be
published.
WEEK OF JUNE 23, 2008 [No. 746]
Very high energy gamma rays emitted from 5 billion light years away detected:
an international team of scientists from the Max Planck Institute for Physics
in Munich and elsewhere has detected a flare of VHEGRs created over 5 Byrs ago
in the Radio Quasar 3C 279.
This is the oldest such burst of gamma rays ever detected. These GRs, with
energies between 80 and 500 GeV, traveled through the extragalactic background
light (EBL), which is a strong absorber of such gamma rays. A conclusion of the
measurements is that most current theories tend to over estimate the density of
the EBL. Gamma-ray telescopes might be used to trace the evolution of the EBL
much farther back in the history of the universe than expected before.
For more information:
Science, June 27 (2008) page 1752; Physicsworld, June 26 (2008).
X-ray diffraction microscopy of a single virus:
scientists from UCLA have used X-rays to image single viruses by separating the
diffraction pattern of the virus from that of their surroundings. The intensity
of the resulting diffraction pattern is measured and the relative phases of the
X-rays within the pattern are recovered by use of an algorithm. The new
technique allows obtaining diffraction patterns of unstained viruses whose
molecular masses are a thousandth of previous specimens. The group has generated
high-contrast images of single viruses with a resolution of 22 nm. They used a
coherent beam of X-rays in a synchrotron beam line but the technique could be
used with small-scale lab X-rays sources as well.
For more information:
Physicsworld, June 25 (2008).
WEEK OF JUNE 16, 2008J [No. 745]
Binding occurs when a protein spontaneously takes the right shape:
scientists from the Max Planck Institute for Biophysical Chemistry in Goettingen
and Vanderbilt University in Nashville have used NMR to map out all possible
shapes of free ubiquitin, a protein found in many living cells. The rather new
NMR technique used here can follow the positions of atoms in a molecule on time
scales for up to several microseconds (traditional NMR can only detect motion on
nanosecond time scales). The team compared the structural ensemble of free
protein shapes with the 46 shapes that ubiquitin is known to adopt when bound
with larger structures (bound proteins have different shapes than their free
counterparts). Free proteins are observed to fluctuate between many different
shapes in the absence of a binding partner and the group discovered that every
one of the bound shapes also occurred in the free protein. They concluded that
no induced-fit motions are required for ubiquitin to adapt to its binding
partners (this theory prevalent for over fifty years claims that a free protein
is coaxed by its binding partner to undergo a gradual change in its shape during
the binding process). Conformational selection has been hard to establish until
now because standard techniques such as X-ray diffraction and conventional NMR
cannot identify the large number of short-lived shapes that a free protein can
adopt.
For more information:
Science, June 13 (2008) pages 1471 and 1421; Physicsworld, June 17 (2008).
WEEK OF JUNE 9, 2008 [No. 744]
Artificial protein refolding shown:
scientists from the University of Massachusetts at Amherst have devised Au
nanoparticles coated with 2-(10-mercaptodecyl) malonic acid and used them to
refold thermally denatured proteins. Activity assays and circular dichroism
spectroscopy have shown that the proteins refold into nearly native
conformations. It needs to be shown if this technique can be used to refold
proteins from chemically denatured states, as is often required for
biotechnology applications. The nanoparticles prevent aggregation of unfolded
proteins by binding to positively charged residues. Removing the nanoparticles
by increasing the salt concentration of the solution frees the proteins to
refold.
For more information:
Chem. Eng. News, June 9 (2008) page38; Chem. Commun., to be published (2008).
New ranked strongest chemical base:
an international team lead by researchers from the University of Minnesota has
discovered the world's strongest base, the gas-phase lithium monoxide anion,
LiO-. The compound wins out over the methyl
anion, CH3-, the previous
titleholder for three decades. CH3-
until now had the highest measured affinity of any compound to regain a lost
hydrogen ion, making it the strongest base. The team synthesized LiO- by using Ar atoms to fragment LiC2O4- in
an electrospray ionization mass spectrometer. The process sequentially knocked
out CO2 and CO molecules to form LiO-. Thermodynamic measurements on LiO- confirmed its record basicity (LiOH is about 9
kcal/mol or 2% less acidic than CH4).
For more information:
Chem. Eng. News, June 9 (2008) page 10; Proc. Natl. Acad. Sci. USA, June 3
(2008) page 7647.
WEEK OF JUNE 2, 2008 [No. 743]
Solid state entanglement at room temperature:
an international team of scientists lead by scientists from Stuttgart University
has demonstrated the creation of bipartite- and tripartite-entangled quantum
states in a small quantum register consisting of individual 13C nuclei in a diamond lattice. Individual nuclear
spins are controlled via their hyperfine coupling to a single electron at a
nitrogen-vacancy defect center. They shine laser light placing some nuclei into
a certain quantum state. By applying RF pulses they drive the spin of the nuclei
to become entangled with one another. Quantum correlations are of high quality
and persist on a millisecond time scale even at room temperature as required for
quantum operations.
For more information:
Science, June 6 (2008) page1326; Physicsworld, June 5 (2008).
Production of single crystals with a large percentage of reactive facets:
Australian and Chinese researchers have synthesized uniform anatase
TiO2 single crystals with a high percentage
(47%) of {001} facets using HF acid as a morphology controlling agent. On
the basis of theoretical predictions they have demonstrated that in
fluorine-terminated surfaces the stability configuration, where the
thermodynamically stable {101} facets dominate with a percentage of 94% over
the more reactive {001} facets, can be reversed. The fluorated surface can be
easily cleaned using heat treatment without altering the crystal structure and
morphology.
For more information:
Chem. Eng. News, June 2 (2008) page 12; Nature, May 29 (2008) page 638.
WEEK OF MAY 26, 2008 [No. 742]
Room temperature Terahertz laser:
researchers at Harvard and elsewhere in the US and Switzerland have made the
first room-temperature coherent terahertz source based on commercially available
semiconductor technology. Until now, the only compact semiconductor lasers to
emit light at terahertz wavelengths were QCLs (quantum cascade lasers) and did
so at below 200 K. The new QCL lasers are a few mm's in size, are electrically
driven, and emit several nanowatts at room temperature, microwatts at 259 K
(thermoelectric cooler temperature), and milliwatts (by optimizing the
semiconductor nanostructure layers of the laser's active region and by improving
the extraction efficiency of the terahertz radiation).
For more information:
Physicsworld, May 28 (2008); Appl. Phys. Lett., May 28 (2008) 211104.
Nanotoxicology shown in cases:
scientists at the University of Edinburgh have injected 50 µg of rigid
multiwalled carbon nanotubes (MWNTs) into the abdominal cavity of mice and
observed their effect on the mesothelial layer of cells that line the cavity.
They found that when MWNTs were straight and longer than 20 m, they caused the
same type of inflammation and granuloma (scar formation) as asbestos. In
contrast, shorter MWNTs, tangled nanotube aggregates, and nanoparticulate carbon
black, did not cause any inflammation or granuloma formation. The indication is
that toxicity is a function of size and shape, not chemistry.
For more information:
Chem. Eng. News, May 26 (2008) page 9; Nat. Nanotechnol., to be published
(2008).
WEEK OF MAY 19, 2008 [No. 741]
Practical polariton light emitting diode:
researchers at the University of Crete in Greece have fabricated a semiconductor
polariton LED that works at near room temperature and is electrically driven
(rather than operating at cryogenic temperatures and being powered by a laser
like its predecessors). A polariton is a quasiparticle consisting of an exciton
(electron-hole pair) and a photon (which is emitted when the electron and hole
recombine). When a photon is emitted, it remains trapped in the material and
creates another exciton so the cycle is repeated. Photons are trapped in a tiny
microcavity that is created between two highly reflecting Bragg mirrors.
Excitons are trapped in quantum wells placed at the two ends of the microcavity
to enhance their coupling to the photons. Metal contacts are formed at the
bottom and on the top of the device to inject electrons and holes respectively.
The fabrication process used molecular beam epitaxy techniques. The group
created an electron-hole pair in an InGaAs quantum well with distributed Bragg
reflectors in both sides. Then, they constrained the polariton with highly
reflective layers of GaAs and AlAs in both ends of the system. Finally they
applied and electrical current to excite the system to emit light directly from
polariton states creating a steady source of light at -38C (polariton
electroluminescence had previously been achieved only at -196 C).
For more information:
Nature, May 15 (2008) pages 372 and 297; Chem. Eng. News, May 19 (2008) page 9;
Physicsworld, May 19 (2008).
WEEK OF MAY 12, 2008 [No. 740]
Biological eyes can see circularly polarized light:
German and Australian researchers have shown that mantis shrimp can detect any
possible combination of linear and circular polarization. These creatures have
two spherical compound eyes, each of which comprises hundreds of smaller eyes
organized into three substructures, two hemispheres separated by a mid-band. The
team shone light of different linear and circular polarizations on the three
substructures of the small eye units and measured the electrical response of the
photoreceptors within. They discovered that the photoreceptors in the hemisphere
respond to light with different linear polarizations, while the mid-band was
sensitive to circularly polarized light. They detect circular polarization in
the mid-band region by first passing light through a biological cell that
appears to act as a quarter wave plate converting circularly polarized light to
linearly polarized light. This light is then detected by cells sensitive to
linearly polarized light. This ability allows the shrimp to perceive very
subtle changes in light polarization and improve their view of their
environment. Some of their prey are transparent and hard to see in sea-water,
except that they are packed with polarizing sugars which, consequently, can be
detected. Since light reflecting from mantis shrimp is circularly polarized,
polarization vision might also be involved in the mating process.
For more information:
Physicsworld, May 14 (2008).
WEEK OF MAY 5, 2008 [No. 739]
A memresistor fabricated:
researchers at the HP labs in Palo Alto have attached a layer of doped
TiO2 to a layer of undoped TiO2 and found that it exhibits
hyterisis in current-voltage loops in the way Leon Chua predicted in 1971 the
missing memresistor would. This element now completes the fundamental quartet of
two-terminal circuit elements (resistor, capacitor, inductor, and memresistor).
While a resistor opposes charge flow, an inductor opposes charge flow change,
and a capacitor stores charge, the memresistor remembers the flowed through
charge and changes its resistance accordingly. The group has reported that
memresistance arises naturally in nanoscale systems where solid-state
electronics and ionic transport are coupled under an external bias voltage. The
fabrication of this non-linear resistor with memory followed a previously
developed analytical model by the same group consisting of a thin piece
semiconductor containing two different regions, a highly doped region of low
resistance and a zero-doped region of high resistance. When a voltage is applied
across the semiconductor, it causes some of the dopants to drift so that the
combined resistance changes, thereby producing the characteristic hysteresis
effect of memresistance. Anomalous behaviors observed in nano-electronics over
the last decade might be understood as a manifestation of memresistive dynamics.
Memresistors may allow a significant increase in functional density over that
achieved by transistors.
For more information:
Nature, May 1 (2008) pages 80 and 42; Physicsworld, April 30 (2008).
WEEK OF APRIL 28, 2008 [No. 738]
A full human genome sequenced at 100 times lower cost:
a group lead by Baylor College of Medicine and 454 Life Sciences researchers
have completed the sequence (6 gigabases) of the diploid genome of James D.
Watson, to 7.4-fold redundancy in two months using massively parallel sequencing
in picoL size reaction vessels at a percent of the cost of traditional capillary
electrophoresis methods (total cost ~$1M).
For more information:
Nature, April 17 (2008) pages 872, 819, and 788.
Giant piezoresistance observed:
European scientists in France, Switzerland and UK have recorded the largest ever
change in a bulk material's electrical resistance brought about by stretching
the material at room temperature. A metal / Silicon hybrid piezoresistance
yielded a gage factor (change in resistance per unit of strain) of 900. Simple
metal-foil piezomaterials gage is typically 2. Expensive Si-based piezoresistors
now have a gage of 100.
For more information:
Physics News Update, May 1 (2008); Phys. Rev. Lett., April 11 (2008).
Auroral lights are polarized:
European researchers from France, Netherlands and Norway have confirmed that
auroral light is polarized as claimed some fifty years ago by Bob Duncan (and
set aside by prevailing wisdom since). Duncan considered that electrons from the
solar wind trapped in the Earth's magnetic field collide with atoms at 200 km
height leaving them in an excited quantum state. When returning to the ground
state they fluoresce with polarized light.
For more information:
Physicsworld, May 1 (2008); Geophys. Res. Lett, to be published (2008).
WEEK OF APRIL 21, 2008 [No. 737]
Some marine organisms increase ocean calcification as CO2 rises:
an international team lead by European researchers has obtained laboratory
evidence that calcification for coccolithophores is significantly increased by
high CO2 partial pressures. Field evidence from the deep ocean is
consistent with these laboratory conclusions, indicating that over the past 220
years there has been a 40% increase in average coccolith mass. The findings
show that coccolithophores are already responding ( they produce about a third
of CaCO3 in today's oceans) and will probably continue to respond to
rising atmospheric CO2 partial pressures which has important
implications for biogeochemical modeling and the future of oceans and climate.
For more information:
Science, April 18 (2008) page 336; Chem. Eng. News, April
21 (2008) page 43.
The Poisson ratio of buckypaper can be simply tuned:
US and Brazilian researchers have found that the in-plane Poisson's ratio
(lateral contraction over stretch) of carbon nanotube sheets can be varied from
positive to negative (width increases when stretched) by mixing single-walled
and multi-walled nanotubes. Density-normalized sheet toughness, strength, and
modulus were substantially increased by this mixing. Theory predicts the sign
and magnitude of the Poisson's ratio from the relative ease of nanofiber bending
and stretch. Increasing the amount of MWNTs in the paper produces a sharp
transition from 0.06 to -0.20 in Poisson's ratio.
For more information:
Science, April 25 (2008) page 504; Physicsworld, April 24
(2008).
WEEK OF APRIL 14, 2008 [No. 736]
Warping of space - time by quasars shown:
an international team lead by Finnish researchers have provided an important
test of general relativity at the very strong gravitational field limit by
analyzing the OJ287 quasar. This distant galactic core emits two opposite bright
optical bursts about every 12 yrs. The group suggested in 1988 that the emission
is powered by a primary black hole with mass ~ 18Bsuns. A second black hole
some
200 times lighter passes through matter in the accretion disk of the primary
black hole twice per orbit releasing a burst of energy. Based in two decades of
observations and modeling the group was able to predict the 2007 burst with a
day precision. The results are consistent with the quasar being a binary black
hole system with the suggested masses and a precession of the secondary black
hole of 39 deg / period ( vs. a precession of 0.1 deg / century in the case of
Mercury due to the Sun-induced local space - time warping). The analysis
suggests that the binary system is losing orbital energy by emitting
gravitational waves. When this emission is not included in the calculation, the
quasar outburst is predicted to occur 20 days later, providing indirect support
for gravitational waves. This quasar seems now to be the brightest known source
of gravitational waves in the universe.
For more information:
Nature, April 10 (2008) page 851; Physicsworld, April 16 (2008).
WEEK OF APRIL 7, 2008 [No. 735]
Post-perovskite responsible for Earth's rotation fluctuations:
researchers at the Tokyo Institute of Technology prepared samples of perovskite
(common MgFe silicate mineral) and tested its electrical conductivity in a
laser-heated diamond anvil cell. At the high temperature and pressure expected
at the core-mantle boundary inside Earth, the scientists observed the mineral
undergo a phase transition to form post-perovskite. This transition is
accompanied by a shift in the electronic structure of metal atoms, causing the
conductivity to jump two orders of magnitude. It is a post-perovskite layer,
perhaps 300-km thick, just above the core-mantle boundary that could give rise
to Earth's observed rotational fluctuation.
For more information:
Chem. Eng. News, April 7 (2008) page 51; Science, April 4 (2008) page 89.
3 D mapping of magnetic fields inside solids with micron resolution:
scientists in the Berlin Institute of Technology and elsewhere in Germany have
used a beam of polarized neutrons from a nuclear reactor beamline to irradiate
samples. As the neutrons travel through a sample, their magnetic moments rotate
around the magnetic fields they encounter and the direction of their spin
changes. The researchers measure the different spin angles, which depend on the
strength of the magnetic fields traversed by the neutrons. The measured values
are converted into intensities by a polarization analyzer, located behind the
sample. Next, a position-sensitive detector measures these intensities to make a
map of the magnetic fields inside the sample.
For more information:
Physicsworld, April 8 (2008); Nature Physics on line.
WEEK OF MARCH 31, 2008 [No. 734]
Groups of spines are the functional units of brain plasticity:
researchers at the Howard Hughes Medical Institute in Virginia have investigated
the neural basis of plasticity at a fine scale activating individual dendritic
branches (each receiving thousands of excitatory synapses most of them on
dendritic spines).They mimicked precisely patterned synaptic activation using
laser stimulation of dendritic spines. Caged neurotransmitter glutamate is
released from the cage by the laser, allowing glutamate to act locally on the
dendritic spine. The laser is moved rapidly from one spine to the next to
precisely mimic patterned synaptic activation. They show that when clusters of
synapses on a dendritic branch are stimulated simultaneously, under conditions
thought to mirror brain states during learning, repeated activation leads to
gradual changes in the response of the branch. They observe that the coupling
between local dendritic spikes and the soma of rat hippocampal CA1 pyramidal
neurons can be modified in a branch-specific manner through an NMDA
receptor-dependent regulation of dendritic Kv4.2 potassium channels. This shows
the existence of an effective form of local dendritic spike plasticity. Branch
strength potentiation represents a new form of information storage and memory
formation.
For more information:
Nature, March 27 (2008) pages 436 and 420.
WEEK OF MARCH 24, 2008 [No. 733]
Nanocrystals do the trick for better thermoelectrical properties:
researchers at Boston College and MIT have made a significant breakthrough in
thermoelectricity by increasing the capability of one of the main thermoelectric
materials by 20% after more than fifty years of trials. Specifically the
figure of merit ZT (gives how good electricity conductor and how poor heat
conductor the material is) for the BiSbTe has been increased from 1.0 to 1.2 at
room temperature. The procedure involved milling the material into a fine powder
that contained nanoparticles measuring 20 nm across and hot-pressing the powder
into nanocrystalline ingots. They found that ZT peaks at 1.4 at 100 C.
Electrical transport measurements on the ingots, together with microstructure
and computer simulations, showed that the ZT improves thanks to the low thermal
conductivity caused by increased phonon scattering at grain boundaries and
defects in the material. However, the electrical conductivity of the material is
not affected significantly by grain boundaries and defects. The high ZT in the
temperature range 25 - 250 C makes these materials promising for cooling and
waste heat recovery applications.
For more information:
Physicsworld, March 22 (2008); Science, on line.
Single photon logic gates on Silicon:
scientists at the University of Bristol have built the first logic gates on a Si
chip that can process individual photons. The chip, which measures several
millimeters across, reproduces an earlier version of the gate that occupied
several square meters of space on an optical bench. Instead of mirrors and beam
splitters, they used coupled waveguides- micrometer-wide channels of transparent
silica that can be fabricated on Si wafers using standard microelectronics
techniques.
For more information:
Physicsworld, March 27 (2008); Science, on line.
WEEK OF MARCH 17, 2008 [No. 732]
New class of high temperature superconductor compounds discovered:
researchers at the Tokyo Institute of Technology have reported that a layered
Fe-based compound LaOFeAs undergoes superconducting transition under doping with
negative F ions at the double negative O site. The transition temperature (Tc)
exhibits a trapezoidal shape dependence on the atomic fraction of the negative F
ion, with the highest Tc ~26K at 0.04-0.11 atomic fraction (negative F ion
content). The crystalline material comprises layers of La and O sandwiched
between layers of Fe and As and is doped with F ions. The new superconductor
proves that high Tc superconductivity is not limited to Cu oxides and a few
other compounds based on U, Ce and Pu.
For more information:
Physicsworld, March 20 (2008); J. Am. Chem. Soc., Feb. 23 (2008) page 3296.
Single photon satellite communication demonstrated:
a team of Italian and Austrian scientists has shown that it is possible to send
single photons from a satellite to a receiving station on Earth. The work paves
the way for global quantum cryptography and more rigorous tests of quantum
mechanics. By bouncing the beam off the satellite orbiting at 1,500 km, it is
calculated that they receive an average of 0.4 photons / pulse. By precisely
calculating when each pulse is to return to the observatory (accounting for the
changing position of the satellite), they were able to show that the detected
photons are those transmitted by the telescope and not stray photons from
background sources.
For more information:
Physicsworld, March 20 (2008); to be published at The New Journal of Physics.
WEEK OF MARCH 10, 2008 [No. 731]
The cosmic neutrino blanket confirmed:
analysis of five year data from the NASA's WMAP (Wilkinson Microwave Anisotropy
Probe) have shown the faint signal in the cosmic microwave background that is
associated to the neutrino sea liberated a second after the Big Bang. They have
also provided an independent estimate of the number of neutrino families in
nature (4.4 ± 1.5) and have constrained the combined mass of all types of
neutrino to be less than 0.61 eV. The new combined limits imposed by the data on
spectral index (this parameter is related to the slope of the angular power
spectrum once its oscillatory features have been removed and is set to < 1.0
as in simple inflation models) and on gravitational waves (these are produced by
motion on the quantum scale and blown up during inflation and can contribute <
20% of the total temperature anisotropy) rule out a swathe of inflation
models. The age of the Universe has been set to 13.73 ± 0.12 Gyr and
95% of the Universe content has been set as dark matter and energy.
According to the analysis of the data, at the time of recombination when atoms
were formed and photons decoupled from the previous plasma, neutrinos made up
10% of the Universe, photons 15%, atoms 12%, dark matter 63%,
and dark energy was negligible. Today, < 1% of the Universe is made of
neutrinos and photons, 4.6% is atoms, 23% dark matter and 72% dark
energy.
For more information:
Physicsworld, March 12 (2008); to be published in The Astrophysical Journal.
WEEK OF MARCH 3, 2008 [No. 730]
Coherent soft XR laser:
scientists at Colorado Sate University in Fort Collins have demonstrated an
almost fully coherent soft X-ray laser. The laser operates at wavelengths of
18.9 nm and 13.9 nm. The latter is fine enough for EUV lithography which will be
needed to manufacture the generation of chips that are to become available
around 2011 with features that are just 22 nm, half as much as the most advanced
today. The group generated low-energy seed pulses of EUV light by firing a Ti:Sa
laser through a Ne gas cell. The generated harmonics were fed to an amplifier
(plasma made by irradiating polished Mo or Ag slabs with pulses from another
laser) that boosted the power only of the desired wavelengths (Mo amplified the
18.9 nm line and Ag boosted the 13.9 nm line).
For more information:
Spectrum, March (2008) page 14.
Marine predators use Levy walks for foraging decisions:
an international team lead by English researchers from the Marine Biological
Association at Plymouth, have analyzed over a million movement displacements
recorded from animal-attached electronic tags to show that diverse marine
predators (sharks, bony fishes, sea turtles and penguins) exhibit Levy-walk-like
behavior close to a theoretical optimum. Prey density distributions also display
Levy-like fractal patterns, suggesting response movements by predators to prey
distributions. Simulations show that predators have higher encounter rates when
adopting Levy-type foraging in natural-like prey fields compared with purely
random landscapes.
For more information:
Nature, February 28 (2008) page 1098.
WEEK OF FEBRUARY 25, 2008 [No. 729]
Ia supernovae produced by accretion in binary stars:
German and Dutch scientists have discovered a luminous source of low-energy
X-rays in pre-supernova archival X-ray images at the position of the recent type
Ia supernova (2007on) in the elliptical galaxy NGC 1404. Deep optical images
(also archival from NASA's Chandra X-ray-observatory satellite) show no sign of
this object. The researchers conclude that the X-ray source is the progenitor of
the supernova, which favors the accretion model for this supernova. Type Ia
supernovae are exploding stars that are used to measure the accelerated
expansion of the Universe and are responsible for most of the Fe ever produced.
It is generally agreed that the exploding star is a white dwarf (degenerate
star) in a binary system; however it is not clear how the explosion is induced.
The discovery here favors the idea that an exhausted white dwarf accretes
material from its normal H-burning star companion until it exceeds the
Chandrasekhar mass (1.39 x mass of Sun), collapses and explodes. The other
option where two white dwarfs merge causing catastrophic collapse and explosion
seems now less probable. The host galaxy is older (6-9 Gyr) than the age at
which the explosions are expected with accretion in single degenerate binary
systems.
For more information:
Nature, February 14 (2008) pages 802 and 775.
WEEK OF FEBRUARY 18, 2008 [No. 728]
Solar systems similar to our own might be common:
an international team lead by Ohio State University scientists have detected a
multiple-planet system using a gravitational microlensing technique. The star
has half mass of the Sun and is 5000 light years away. The inner planet has a
mass ~0.71 that of Jupiter and orbits at 2.3 AU from the star (vs. 5.2 for
Jupiter). The outer planet is ~0.90 as massive as Saturn and lies at 4.6 AU
from
the star (vs. 9.5 AU for Saturn). The ratios of the planet's masses and of their
distances from the star are similar to those of Jupiter and Saturn. Even the
warmth that the dimmer star sheds on the planets is similar to what the Sun
sheds on Jupiter and Saturn. The discovery could not have been possible with
other techniques.
For more information:
Science, February 15 (2008) pages 927 and 885; Physicsworld, February 14 (2008).
Ball lightning produced by ejected burning Si nanoparticles:
sraeli and French researchers have used a beam line at the ESRF, European
Synchrotron Radiation Facility, to make fireballs in a microwave cavity and
probe them with 12.5 keV X-rays at atmospheric pressure. They created a hotspot
by concentrating microwaves with a Cu electrode, then touching the electrode to
a borosilicate glass substrate. Upon retracting the electrode, a molten drop
detached and vaporized into a buoyant fireball. Small-angle X-ray scattering
revealed that the particles contained in the fireball are approximately 50 nm in
diameter and form a radiative dusty plasma with n~109
particles/cm³ and T ~1000 K.
For more information:
Physics Today, February (2008) page 18; Phys. Rev. Lett., upcoming article.
WEEK OF FEBRUARY 11, 2008 [No. 727]
Alzheimer's plaques can grow rapidly:
scientists from the Harvard Medical School and Washington University have
studied the kinetics of formation of extracellular protein deposits (amyloid
plaques) using multiphoton laser confocal microscopy in a mouse model of
Alzheimer's disease. They have observed remarkably different kinetics of plaque
formation from that expected. New plaques formed in only 24 hours and their
size and final characteristics stabilized within a week. The mature plaques
originate from smaller amyloid deposits (microplaques) that support a fast but
eventually stable growth of the plaques. In the early stages of the Alzheimer's,
microplaques can damage neighboring axons and dendrites within days.
For more information:
Nature, February 7 (2008) pages 720 and 638.
Spectroscopy of anti-hydrogen in electromagnetic confinement:
scientists at CERN have detected for the first time the presence of
anti-hydrogen atoms in a combined Penning-Ioffe trap. Anti-protons are created
in high energy collisions while positrons are produced in a radioactive source.
The Penning trap holds the positrons and antiprotons to form anti-hydrogen atoms
that are then confined in the Ioffe trap for analysis. Although there is not yet
evidence of trapped anti-toms, the researchers have carried high-precision
spectroscopy studies to prove that anti-atoms are produced and that the number
of anti-atoms increases when the Ioffe trap is turned on.
For more information:
Physics News Update, February 13 (2008); Phys. Rev. Lett., upcoming article.
WEEK OF FEBRUARY 4, 2008 [No. 726]
Abiogenic source of mantle-derived hydrocarbons:
cientists from the University of Washington and elsewhere in the US and
Switzerland have demonstrated the existence of hydrocarbons (HCs) dissolved in
hydrogen-rich fluids venting at the ultramafic-hosted Lost City hydrothermal
vent field in the Atlantic Ocean. They have uncovered a distinct inverse trend
in the stable carbon and hydrogen isotopic composition of C1 to C4 hydrocarbons
compatible with FTT (Fischer-Tropsch) genesis which is the lengthening of carbon
chains through a series of inorganic reactions. It has been difficult to
demonstrate a purely mantle, abiogenic origin of previously identified HCs in
the face of abundant biogenic HCs. Radiocarbon evidence rules out seawater
bicarbonate as the C source for the FTT reactions, suggesting that a
mantle-derived inorganic C source is leached from the host rocks. Mantle methane
seems to be yielding HCs through these inorganic reactions. The group concludes
that the abiotic synthesis of HCs in nature may occur in the presence of
ultramafic rocks, water, and moderate amounts of heat. Because this system is
likely representative of many similar systems in the oceans, an abundant source
of mantle-derived HCs may be present on Earth now and in its early history.
For more information:
Science, February 1 (2008) pages 604 and 545.
WEEK OF JANUARY 28, 2008 [No. 725]
The first radio made of nanotubes:
scientists from the University of Illinois have built radio frequency SWNT
(single wall nanotubes) analog electronic devices, such as narrow band
amplifiers operating in the VHF frequency band with power gains as high as 14
dB. They fabricated nanotube transistors, in which SWNT devices provide all the
key functions, including resonant antennas, fixed RF amplifiers, RF mixers, and
audio amplifiers. Unlike previous nanotube radios, which produced very weak
signals that needed further amplification, the team was able to listen to a
local broadcast on headphones connected directly to a nanotube transistor.
For more information:
Proc. Natl. Acad. Sci. USA, January 28 (2008); Physicsworld, January 31 (2008).
Fine tuning of porosity:
scientists from the University of Tokyo have demonstrated control of pore nature
in library synthesis of a class of porous crystalline materials. The bimolecular
porous material has two molecular components, one of which can be easily
replaced (like changing a cartridge in a pen). The flexibility allows the
absorption properties of the crystalline metal-organic compound to be
fine-tuned. They prepared a porous system in which an organic ligand donates
electrons to ZnI forming coordination bonds. The resulting crystal structure
traps aromatic molecules (triphenylenes) via non-covalent interactions to form
two types of channels that recognize and bind small molecules. Which molecules
are trapped depends on the chemical groups attached to the triphenylenes. The
recognition properties of the channels can be fine-tuned by replacing the
triphenylenes with others that have different chemical groups attached.
For more information:
. Am. Chm. Soc., November 22 (2007); Nature, January 24 (2008) page 410.
WEEK OF JANUARY 21, 2008 [No. 724]
Protons identified as fast neurotransmitters:
researchers at the University of Utah have shown that protons can act as a
direct transmitter from intestinal cells to stimulate muscle contraction. The
group reached this conclusion while studying muscle contractions associated with
defecation in Caernorhabditis elegans worms. They found that the contraction of
intestinal muscles depends on two types of proteins: proton transporters
(sodium/proton exchangers, ubiquitous in both worms and man) on the exterior of
the intestine and proton receptors on the surface of muscles surrounding the
intestine. Caged protons released by the transporters bind to the receptors,
which open channels to admit Na ions into the muscle cells. The influx causes
the muscles to contract.
For more information:
Chem. Eng. News, January 14 (2008) page 10; Cell, January 11 (2008) page 149.
Synthetic organism within grasp:
scientists from the Venter Institute in Maryland have assembled a synthetic
genome replicating Mycoplasma bacterium's genetic structure. The team strung
together nucleotides to include all the genes of the naturally occurring
bacterium but disrupted the genes that would enable it to infect other
organisms. Previously last June the Institute inserted the DNA of one species of
bacteria into cells of another bacteria species. That process booted up the
genome of the donor bacteria, sparking it to life. They hope to use a similar
trick to boot up the artificially created genome to synthesize a living organism
later this year.
For more information:
Wall Street Journal, January 25 (2008) page B3; Science, on line.
WEEK OF JANUARY 14, 2008 [No. 723]
Our galactic antimatter has been located at central binary stars:
an international team of researchers from the CNRS at Toulouse and from
elsewhere have uncovered a distinct asymmetry in the 511-keV line emission
coming from the inner Galactic disk (~10 - 50 deg. from the Galactic
Center).
This asymmetry resembles an asymmetry in the distribution of low mass X-ray
binaries (pairs of either black holes or neutron stars) with strong emission at
photon energies > 20 keV, indicating that they may be the dominant origin of the
positrons. The distribution of the annihilation line radiation has been analyzed
using more than four years of spectroscopy data from the INTEGRAL satellite.
Although it had long been suspected that the electron-positron pair plasmas may
exist in X-ray binaries, it was not evident that many of the positrons could
escape to lose energy and ultimately annihilate with electrons in the
interstellar medium and thus lead to the emission of a narrow 511-keV line. It
is evaluated that up to a few times 1041 positrons escape per second
from a typical hard low-mass X-ray binary. Positron production at this level in
the Galactic bulge would reduce (and possibly eliminate) the need for more
exotic explanations, such as those involving dark matter.
For more information:
Nature, January 10 (2008) pages 159 and VI
WEEK OF JANUARY 7, 2008 [No. 722]
A new generation spectroscopy:
cientists at NIST-Boulder have done spectroscopy of a gas using optical
frequency combs. The experiment examines the gas absorption on 155,000 lines
spanning a wavelength range of 125 nm. The spectral line precision is 1 Hz (for
spectral frequencies of 1014 Hz) and that compares with tens of MHz
characterizing standard spectroscopy techniques. The spectroscopy work
accomplished is equivalent to simultaneously sending 155,000 individual single
frequency lasers through the sample and measuring the resulting amplitude and
phase shift on each individual laser after absorption when any given line is
resonant with any of the many quantum energy levels of the gas. Moreover, the
spectrum is measured rapidly, using no moving mechanical parts. The group uses
highly stabilized mode-locked lasers that emit femtosecond pulses at repetition
frequencies of GHz. Special optical paths and techniques are used to make the
comb teeth as fine and perfectly and evenly spaced as possible. The comb used
for the spectroscopy is mixed with a second carefully-crafted frequency comb to
produce a beat frequency pulse which is radiated into the gas. This then can be
measured with conventional electronics to determine the specific absorption
characteristics of the more than hundred thousand comb lines used in the new
spectroscopy technique.
For more information:
Physics News Update, January 11 (2008); Phys. Rev. Lett., January 11(2008).
NOTE: previous Research News (since WEEK OF MARCH 1, 1994 [No. 1],
around the time when the Quantum Cascade Lasers were demonstrated at
AT&T Bell Laboratories in Murray Hill, N.J., as promising MIR
solid-state room temperature sources that would enable laser
spectroscopy in the spectral region where fundamental
rotational-vibrational transitions of most molecules take place) not posted.
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